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While solar (photovoltaic) electricy is a multi-billion dollar industry, solar hydrogen - the direct generation of hydrogen by solar irradiation - is in its infancy. This book offers the latest knowledge to scientists, engineers, and entrepreneurs involved in photoelectrochemical systems and nanotechnology for the generation of hydrogen. The technical content addresses the current status and prospects of R&D activities, major achievements, technological limitations and challenges, the latest advances in semiconductor nanostructures, device fabrication, modeling, simulation and characterization techniques. The book is a major, comprehensive reference source for solar hydrogen.